How Bakelite is prepared?

How Bakelite is prepared?

Phenol - formaldehyde polymers are the oldest synthetic polymers. These are obtained by the condensation reaction of phenol with formaldehyde in the presence of either an acid or a base catalyst. The reaction starts with the initial formation of o-and/or p-hydroxymethylphenol derivatives, which further react with phenol to form compounds having rings joined to each other through –CH2 groups. The initial product could be a linear product – Novolac used in paints.

Novolac on heating with formaldehyde undergoes cross linking to form an infusible solid mass called bakelite.