Which of the following has larger bond angle in each pair?

Which of the following has larger bond angle in each pair?
(i) ${{CO}{2}}$,
${ BF }
{ 3 }$
(ii) ${N H }{ 3 }$,
${C H }
{ 4 }$
(iii) $H { 2 }O$,
$H { 2 }S$
(iv) ${ SiF }
{ 4 }$,
$C
{2}H_{2}$

(i) ${ Co }{ 2 }$
(ii)${ CH }
{ 4 }$
(iii) $H { 2 }O$
(iv)$C
{2}H_{2}$